Vol. VI · Proteins and Heat Plate 10 of 11gluten, glutenin, gliadin, kneading, dough, elasticity, extensibility, flour proteinMT

Gluten.

Flour and water, stirred, make a paste. Kneaded, the same paste becomes a dough that stretches and springs back — gluten has formed.

Wheat flour contains about 8–14 % protein, most of it two kinds that do nothing on their own: glutenin, long chains that link end to end, and gliadin, smaller and coiled. Add water and they hydrate; work the mixture and they line up and bond into gluten, a network that is both elastic (glutenin, springing back) and extensible (gliadin, flowing). That network holds the bubbles of a rising bread, gives noodles their bite and makes pastry tough if overworked.

Three things build gluten: protein in the flour, enough water, and time or work — kneading, or simply resting so the proteins link on their own (autolyse and no-knead bread, XXIV.4). Two things hold it back: fat, which coats the proteins, and sugar, which competes for water. The workshop builds a dough.

Below: gluten development against kneading time for bread, all-purpose and cake flour, and your dough with the water, rest and fat you choose (a teaching index, 1 = well developed).

What you will learn
Workshop
Teaching index of gluten development from flour protein, hydration, kneading minutes and resting time, reduced by fat. Flours: bread about 13 % protein, all-purpose about 11 %, cake about 8 %.

Water, work and time

A 12 % protein flour at 65 % water, kneaded eight minutes, reaches a development of 0.63 on this index. Leave out the kneading but add more water and twelve hours of rest — the no-knead method — and it reaches 1.00: given time and water, the proteins link by themselves. Add 30 % fat and the same kneading gives only 0.19, which is why brioche needs long mixing and why shortbread, with lots of butter, low-protein flour and little water (0.06), stays crumbly.

Choose accordingly. Bread and chewy noodles want high-protein flour, enough water and work; cakes and tender pastry want low-protein flour, little mixing and fat to shorten the strands (IX.9, XXV.4). Chinese flours are graded the same way — 高筋 for bread and pulled noodles, 中筋 for dumplings and steamed buns, 低筋 for cakes. Salt tightens gluten a little; acid and enzymes in some ingredients loosen it.

At the stove

Mix 100 g of flour with 60 g of water into a shaggy dough and leave it covered for 30 minutes. Then pull a small piece: it already stretches a little. Knead the rest for five minutes and pull again; it stretches thin enough to see light through — the "windowpane" of developed gluten.

Chinese cooks wash dough under water to remove the starch and keep the gluten itself, which is steamed, fried or baked as 面筋 and 烤麸 — a protein food made entirely from this network.

Terms

Glutenin
Long wheat proteins that link into elastic chains.
Gliadin
Smaller wheat proteins that make dough extensible.
Gluten
The network glutenin and gliadin form with water and work.
Autolyse
Resting flour and water before kneading, letting gluten develop on its own.
Gluten needs protein, water and work or time; fat and sugar hold it back. Chewy wants more, tender wants less.

Sources

  1. A teaching value chosen for the course: the right order of magnitude and shape, not a measurement of a particular food.
  2. H. McGee, On Food and Cooking: The Science and Lore of the Kitchen, 2nd ed., Scribner, 2004.